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July 29, 2025

Combating Vapour Pressure: Specifying Diaphragm Pumps for Volatile or High-Temperature Liquids

The safe and efficient transfer of volatile or high-temperature liquids presents one of the most significant challenges in industrial fluid management. These challenging fluids, often present in chemical processing, pharmaceuticals, and other critical sectors, demand pumping solutions that can reliably operate without compromising safety or product integrity. A primary concern when handling such liquids is vapour pressure, which can lead to cavitation and operational instability. Diaphragm pumps have consistently proven to be a robust and reliable choice for these demanding applications. Ovell Pump, as experienced diaphragm pump manufacturers, designs and configures its pumps to effectively manage these complexities, ensuring optimal performance and safety in hazardous environments.

Understanding Vapour Pressure and Its Implications

Vapour pressure is the pressure exerted by a vapour in thermodynamic equilibrium with its condensed phases (solid or liquid) at a given temperature in a closed system. For liquids, as temperature increases, so does their vapour pressure. When the pressure within a pumping system drops below the fluid's vapour pressure at that temperature, the liquid can flash into a gas, forming vapour bubbles. This phenomenon is known as cavitation.

In the context of pumping, cavitation primarily occurs on the suction side of a pump where pressure is lowest. As these vapour bubbles travel through the pump and encounter higher pressure regions, they rapidly collapse. This collapse generates intense shockwaves and micro-jets that can cause significant damage to pump components, leading to:

  • Erosion and Pitting: The violent collapse of bubbles erodes the pump's internal surfaces, particularly the diaphragms, valves, and pump housing.
  • Reduced Performance: Cavitation disrupts the smooth flow of liquid, leading to erratic flow rates, reduced capacity, and decreased pumping efficiency.
  • Increased Noise and Vibration: The collapsing bubbles create noticeable noise and vibration, indicating operational distress and potential damage.
  • Premature Component Failure: Continuous cavitation significantly shortens the lifespan of pump parts, necessitating frequent maintenance and replacement.
  • Safety Hazards: For volatile or hazardous liquids, cavitation can lead to uncontrolled vapour release, creating fire, explosion, or exposure risks.

Effectively combating vapour pressure and preventing cavitation is therefore paramount for reliable and safe fluid transfer.

Why Diaphragm Pumps Excel with Volatile Liquids

Diaphragm pumps possess inherent design characteristics that make them particularly well-suited for handling volatile, high-vapour-pressure, and high-temperature liquids. Their positive displacement nature and sealless design address many of the challenges posed by these fluids.

  • Positive Displacement Principle: Unlike centrifugal pumps that rely on kinetic energy and are highly susceptible to cavitation from vapour bubbles, diaphragm pumps operate on a positive displacement principle. They displace a fixed volume of fluid with each stroke of the diaphragm. This means they can handle a certain degree of gas or vapour entrainment without losing prime or experiencing significant performance degradation. They simply continue to move the fluid and any entrained gas through the system.
  • Sealless Design: A critical advantage for volatile and hazardous liquids is the sealless nature of the diaphragm pump. The diaphragm acts as a dynamic seal, completely isolating the fluid from the pump's drive mechanism and the external environment. This eliminates the need for rotating shaft seals, which are common leak points in other pump types and a significant concern when dealing with vapours that could escape or ignite. This inherent leak-free operation is a major safety benefit.
  • Gentle Pumping Action: The reciprocating motion of the diaphragm provides a gentle, low-shear pumping action. This minimises agitation and heat generation within the fluid, which is crucial for volatile liquids, as excessive heat can further increase vapour pressure and exacerbate flashing. This gentle action also preserves the integrity of shear-sensitive fluids.
  • Self-Priming Capabilities: Many diaphragm pumps, particularly air powered diaphragm pump models, are inherently self-priming. This means they can draw fluid from below their level without needing to be pre-filled. This capability is advantageous when handling volatile liquids that might flash in the suction line, as the pump can re-establish prime even with some vapour present.
Specific Design and Configuration for Challenging Fluids

Ovell Pump, as one of the leading double diaphragm pump manufacturers, incorporates specific design features and configurations to optimise diaphragm pumps for volatile and high-temperature applications:

Air Operated Diaphragm Pumps (AODD): Air operated diaphragm pumps are frequently the preferred choice for volatile and flammable liquids. Their pneumatic drive means there are no electrical components in contact with the fluid or in the immediate vicinity of potential vapour release, making them intrinsically safe for hazardous (Ex-rated) environments. The air motor's simplicity and robust nature also contribute to reliability in demanding conditions. This makes them a go-to for many air diaphragm pump manufacturers.

Material Selection for Wetted Parts

The materials of construction for the diaphragms, valve balls, valve seats, and pump housing are critical. For high-temperature and chemically aggressive volatile liquids, common choices include:

  • PTFE (Polytetrafluoroethylene): Offers excellent chemical resistance across a very wide range of aggressive chemicals and high temperatures. Often used for diaphragms and valve components.
  • Viton (Fluoroelastomer): Provides good chemical resistance and excellent high-temperature capabilities.
  • Santoprene (Thermoplastic Vulcanizate): Offers good abrasion resistance and flex life for less aggressive chemicals.
  • Stainless Steel (316L): For pump housings and manifolds where metallic compatibility is required.
  • Polypropylene/PVDF: For non-metallic housings offering broad chemical resistance.

Ovell Pump, as an experienced double diaphragm pump manufacturer, guides clients in selecting the optimal material combination based on the specific fluid's chemical composition, temperature, and concentration.

Porting and Manifold Design: Pumps can be configured with specific porting arrangements to facilitate the handling of volatile liquids. For instance, bottom-in/top-out porting allows for gravity draining of the pump, preventing liquid from sitting and flashing in the pump when not in use. Larger port sizes, such as those found on a 2 inch diaphragm pump, can reduce fluid velocity and pressure drop on the suction side, further mitigating the risk of flashing.

Ball Valve vs. Flap Valve: While ball valves are common, flap valves can be used for fluids with suspended solids or higher viscosities, which can also be volatile. The choice of valve type influences flow characteristics and resistance to clogging.

Liquid Backing Diaphragms: Some advanced diaphragm metering pump designs incorporate a liquid backing behind the primary diaphragm. This provides additional support, reduces stress on the diaphragm, and can help maintain a more consistent displacement volume, especially beneficial for precise dosing of volatile chemicals.

External Air Valve Control: For precise flow control of volatile liquids, the air supply to an air operated diaphragm pump can be managed by external controls, allowing for variable speed and flow rate adjustment without altering the pump's internal mechanics. This is crucial for applications requiring a diaphragm metering pump.

System Design and Installation Considerations

Beyond the pump itself, the overall system design and installation play a vital role in successfully handling volatile and high-temperature liquids with diaphragm pumps.

1. Net Positive Suction Head (NPSH)

Maintaining adequate NPSH available (NPSHa) is critical. For volatile liquids, the vapour pressure component of NPSH required (NPSHr) is higher. Therefore, system designers aim to maximise NPSHa by:

  • Flooded Suction: Positioning the pump below the liquid level in the supply tank ensures a positive pressure at the pump inlet, significantly reducing the risk of flashing.
  • Short, Large Diameter Suction Lines: Minimising friction losses in the suction line by keeping it short and using a larger diameter pipe reduces pressure drop, helping to keep the liquid below its vapour pressure.
  • Minimising Fittings: Reducing elbows, valves, and other fittings in the suction line further decreases pressure losses.

2. Vapour Recovery Systems: For highly volatile or hazardous liquids, the system design may incorporate vapour recovery units or closed-loop systems to capture any flashed vapours, preventing their release into the atmosphere and improving safety.

3. Temperature Management: For high-temperature liquids, insulation of tanks and piping can help maintain fluid temperature and prevent heat loss that could lead to condensation or solidification. Conversely, cooling jackets on pumps can be used if the pump itself generates excessive heat that could impact the fluid.

4. Pulsation Dampeners: While diaphragm pumps offer gentle action, their reciprocating nature can create pulsations in the flow. For sensitive downstream processes or to prevent pipe hammer with volatile liquids, installing pulsation dampeners on the discharge side can smooth the flow and protect the system.

5. Clear Diaphragm Pump Diagram: A well-designed diaphragm pump diagram is essential for proper installation, troubleshooting, and maintenance, ensuring all components are correctly integrated for optimal performance with volatile fluids.

Ovell Pump's Expertise in Challenging Fluid Transfer

Ovell Pump is renowned for its commitment to delivering high-performance fluid management solutions, particularly for the most challenging applications. Our expertise as double diaphragm pump manufacturers and air operated diaphragm pump manufacturers is evident in our robust product range designed to combat the complexities of vapour pressure and high temperatures.

  • Application-Specific Solutions: We understand that each volatile or high-temperature fluid application is unique. Our team works closely with clients to assess the specific chemical properties, temperature ranges, and flow requirements to recommend the most suitable diaphragm pump model and material configuration. Whether it's a compact 2 diaphragm pump for precise dosing or a larger diaphragm transfer pump for bulk transfer, we tailor solutions.
  • Quality and Reliability: Ovell Pump's products are manufactured to stringent ISO9001, CE, and FDA certifications, ensuring high quality, durability, and reliable performance. This commitment to excellence minimises the risk of leaks and breakdowns, which is critical when handling hazardous volatile liquids.
  • Comprehensive Product Range: Our portfolio includes a wide array of air powered diaphragm pump models, as well as electric diaphragm pumps for less hazardous or non-flammable volatile liquids, offering versatility to meet diverse industrial needs. This includes specialised diaphragm metering pump units for precise dosing.
  • Technical Support and Service: Ovell Pump provides extensive technical support, from initial consultation and system design assistance to after-sales service. This ensures that our pumps are correctly specified, installed, and maintained to operate safely and efficiently with volatile or high-temperature fluids. Our engineers are proficient in interpreting and advising on complex diaphragm pump diagram layouts.
Conclusion

The effective handling of volatile or high-temperature liquids is a critical aspect of safety and efficiency in numerous industrial processes. Vapour pressure and the risk of cavitation pose significant challenges that traditional pumping technologies often struggle to overcome. Diaphragm pumps, with their inherent positive displacement, sealless design, and gentle pumping action, emerge as the material of choice for these demanding applications. By leveraging the advanced engineering and material expertise of diaphragm pump manufacturers like Ovell Pump, industries can implement robust, reliable, and safe fluid transfer solutions, ensuring continuous operation and protecting both personnel and the environment. Choosing the right diaphragm pump is an investment in long-term operational integrity and peace of mind.